If you are able to send mails using MS Outlook, you can use MS Outlook as a "Outgoing Mail Server" in cBizOne.
 
Please follow the steps in cBizOne:
 
On the main menu of cBizOne click on Tools-->Options-->Email-->Outgoing Mail Server-->Check "Use Outlook to send Mails", click OK.
 
Please make sure to have both Outlook and cBizOne open before sending mails.
 
FYI: By doing so we submit the email to Outlook Outbox folder, and Outlook delivers to your SMTP server.